In a large skillet over high heat, sear chicken until golden brown, 2 minutes on each side. Season with salt and black pepper and place in slow cooker.
Add onions, garlic, carrots, sugar, zest and juice of 1 lemon, thyme, and chicken broth. Season with 1 tsp salt and 1/2 tsp black pepper. Cover with lid and cook on low for 6 to 7 hours, or on high for 3 to 4 hours.
Add peas and cover with lid until warmed through, 2 to 3 minutes. Add zest and juice of remaining lemon. Serve immediately.
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