In a large mixing bowl, pat beef dry with paper towels. Season generously with salt and black pepper.
Preheat a large cast iron skillet over high heat. Drizzle with olive oil and sear meat on all sides until golden brown with a crust, about 8 to 10 minutes. Transfer meat to the slow cooker. Reduce heat to medium and add garlic, onions, carrots, thyme, 1/2 tsp salt, 1/2 tsp black pepper; scrape the pan with a wooden spoon to loosen all browned meat bits and cook for about 3 to 4 minutes. If needed, add a splash of water to fully deglaze the pan; transfer to the slow cooker.
Add mushrooms, barley, stock and soy sauce; cook on low for 8 hours. Meat should be very tender.
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